Introduction
Transmission of energy through a vacuum or using no medium is accomplished by
electromagnetic waves, caused by the oscillation of electric and magnetic fields. They
move at a constant speed of 3x108 m/s. often, they are called electromagnetic
radiation, light, or photons. An electromagnetic radiation, it has both electric and
magnetic field components, which oscillate in a fixed relationship to one another,
perpendicular to each other and perpendicular to the direction of propagation.
The two components making up an electromagnetic radiation are the:
a) Electric field B) Magnetic field
The two fields are always perpendicular to each other and both are perpendicular to the
direction of propagation.
Fig. Electromagnetic wave
The notion that electromagnetic radiation contains a quantifiable amount of energy can
perhaps be better understood if we talk about light as a stream ofparticles,
called photons, rather than as a wave. (Recall the concept known as ‘wave-particle
duality’: at the quantum level, wave behavior and particle behavior become
indistinguishable, and very small particles have an observable ‘wavelength’). If we
describe light as a stream of photons, the energy of a particular wavelength can be
expressed as:
E = hc / λ
where E is energy in kcal/mol, λ (the Greek letter lambda) is wavelength in
meters, c is 3.00 x 108 m/s (the speed of light), and h is 9.537 x 10
-14 kcal/s/mol-1
, a
number known as Planck’s constant.
Because electromagnetic radiation travels at a constant speed, each wavelength
corresponds to a given frequency, which is the number of times per second that a crest
passes a given point. Longer waves have lower frequencies, and shorter waves have
higher frequencies. Frequency is commonly reported in hertz (Hz), meaning ‘cycles
per second’, or ‘waves per second’. The standard unit for frequency is s-1
.
When talking about electromagnetic waves, we can refer either to wavelength or to
frequency - the two values are interconverted using the simple expression:
C
where ν (the Greek letter ‘nu’) is frequency in s-1
. Visible red light with a wavelength
of 700 nm, for example, has a frequency of 4.29 x 1014Hz, and an energy of 40.9 kcal
per mole of photons.
The full range of electromagnetic radiation wavelengths is referred to as
the electromagnetic spectrum.
1.3 Properties of Electromagnetic radiation
The radiated EM radiation has certain properties:
• EM waves travel at the speed of light c
• The electric and magnetic fields are perpendicular to each other.
• The electric and magnetic fields are in phase (both reach a maximum and minimum
at the same time).
• The electric and magnetic fields are perpendicular to the direction of travel
(transverse waves).
Terms Used
Wavelength - Is the distance between any two equivalent points on successive waves.
Wavenumber - Is the reciprocal of the wavelength in centimeters.
Frequency - Is the number of oscillations of the field which occur each second.
Velocity- In a vacuum, the velocity of electromagnetic radiation is 2.9979 x 108 m/s
Amplitude - The height of the wave.
Their wavelengths and the corresponding differences in their energies: shorter
wavelengths correspond to higher energy.
PROBLEM: Calculate wavelength and frequency of waves.
(a) A local radio station broadcasts at a frequency of 91.7 MHz (91.7 x 106 Hz). What is the
Wavelength of these radio waves?
b) What is the frequency of blue light with a wavelength of 435 nm?
SOLUTION:
You are asked to calculate the wavelength or frequency of electromagnetic radiation.
You are given the frequency or wavelength of the radiation.
(a) First rearrange Equation 6.1 to solve for wavelength (λ). Then substitute the known values
into the equation and solve for wavelength.
ʋ = c / λ or λ =c / ʋ
(b) First rearrange Equation 6.1 to solve for frequency (ʋ). Then substitute the known values
into the equation and solve for frequency. Notice that wavelength must be converted to units
of meters before using it in Equation (c = λʋ)
435nm43510 9m
= 4.35 x 10-7 m
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